[AL]partition coefficient experiment ~~ chem神快進
而家做左1個experiment of partition coefficient of acid in ether and water ...做30cm3 ether and 30cm3 water , 1.5g acid
而家又做第2個experiment 就同第1個一樣 但係轉1樣野 就係用60cm3 ether instead
問題 問 which following would be change?
(1) conc. of acid in ether
(2) conc. of acid in water
(3)partition coefficient
我諗1同2 應該會變因為no mole of acid per vol solvent 唔同左
但3 應該唔變...
我個fd話我錯 係應該3個都唔變...why?
我錯定點[]
[ 本帖最後由 octopus001 於 3-12-2008 16:31 編輯 ] 個coeff唔變,咁自然1同2都唔變啦
有錯諶指正
[ 本帖最後由 j32738 於 4-12-2008 18:23 編輯 ]
回復 2# 的帖子
1同2都唔變只係particular case... 咁即係點 可以詳細d嗎 [] Try to use the concept of reaction quotient to think.(Knowing that K is constant at a certain temp.)
Take the case as "add 30 cm3 of ether to the mixture in experiment 1". 酸在水中會電離
酸在水中的電離作用會使更多的酸溶於水中
如果該酸為乙酸
乙酸在乙醚中透過氫鍵結合成二聚物
這個現象也會使較多乙酸溶於乙醚中
但是酸只是固定量...... 原帖由 octopus001 於 4-12-2008 00:24 發表 http://www4.nakuz.com/bbs/images/common/back.gif
問題 問 which following would be change?
(1) conc. of acid in ether
(2) conc. of acid in water
(3)partition coefficient
我諗1同2 應該會變因為no mole of acid per vol solvent 唔同左
應該 全部都唔變 , 係, 冇錯 no.of mole of acid 唔同左 , 同時 volume 都有變 ,
所以conc. of acid 係唔變 . 其實都係看大家理唔理#6 mention 的東西... 原帖由 Zend 於 14-12-2008 15:43 發表 http://www1.nakuz.com/bbs/images/common/back.gif
其實都係看大家理唔理#6 mention 的東西...
zend你用英文譯一次出黎比大家睇@@
因為樓主好似都係用英文問 1,2都係唔會變....的確volume變左....但是溶於ether和water的acid mole一樣改變,ether的volume多左1倍,因此溶於ether的acid亦多左1倍...因此根據公式(mole/volume)=conc.就會不變,同樣water原理都一樣
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